Record number :
71407
Title of article :
Spherical Aromaticity in Fullerenes and the Nucleus-Independent Chemical Shifts at the Cage Centers
Author/Authors :
Aihara، Jun-ichi نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Pages :
-102
From page :
103
To page :
0
Abstract :
Nucleus-independent chemical shifts (NICSs) at the cage centers for closed-shell isolated-pentagon isomers of C82 fullerene lie in the wide range from -11 to +48 although all of the isomers are sufficiently aromatic. This decisively shows that NICS cannot be used as an indicator of spherical aromaticity for fullerenes. NICS is nothing other than the measure of local magnetotropicity. Diatropicity is compatible with aromaticity only for monocyclic (pi)-systems.
Journal title :
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
Serial Year :
2003
Link To Document :
بازگشت