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Title of article :
Application of a new synthesized organic ligand as an ionophore in new nanocomposite carbon paste electrode and investigation its electrochemical interaction with Cd2+ and determination of nano level
Author/Authors :
قاعدي، حامد نويسنده Ghaedi, Hamed , شيرزادمهر، علي نويسنده Shirzadmehr, Ali , هاشمي ، ابوالقاسم نويسنده , , باقري، حسن نويسنده ,
Issue Information :
فصلنامه با شماره پیاپی 0 سال 2011
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Abstract :
In this article a new synthesized organic macrocycl compound “2,2-thio-bis [4-methyl (2-amino phenoxy) phenyl ether]” (TBMAPPE) was used in a new chemically modified carbon paste electrode for determination of Cd2+ ions, as an ionophore. This potentiometric sensor had been fabricated for the rapid determination of Cd2+ based on carbon paste electrode consisting of room temperature ionic liquid (RTIL) 1-Butyl-3-methylimidazolium hexafluorophosphate (BMIM-PF6), multi-walled carbon nanotubes (MWCNTs), TBMAPPE and graphite powder. The electrode exhibits a Nernstian response for Cd2+ ions over a wide concentration range (5×10-8- 1×10-1 mol L-1) with a slope of 29.50±0.10 mV per decade. It has a response time of about 10 s and can be used for a period of 3 months with good reproducibility. Detection limit obtained in the optimal conditions was 7.9 × 10–9 mol L-1. The electrode was successfully used for potentiometric determination of Cd2+ in well water. The pH influence and interference of some cations were also studied.
Journal title :
Iranian Journal of Organic Chemistry
Link To Document :