Record number :
64243
Title of article :
Syntheses and structures of [(Me3N)3SiNHLi]4, (C4H8O)Al[NHSi(NMe2)3]3, ((Me2N)3SiNH)3Al and Li(THF)2+[((Me2N) 3SiNH)4Al]–
Author/Authors :
Cheng، Fei نويسنده , , Lefebvre، Frederic نويسنده , , Bradley، John S. نويسنده , , Archibald، Stephen J. نويسنده , , Supplit، Ralf نويسنده , , Rovai، Riccardo نويسنده , , Lehmann، Christian W. نويسنده , , Kruger، Carl نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Pages :
-1845
From page :
1846
To page :
0
Abstract :
The preparation of lithium tris(dimethylamino)silylamide, [(Me3N)3SiNHLi]4, 2, and its reaction with aluminium trichloride to give tris (dimethylamino)silylamino)(tetrahydrofuran)alane, (C4H8O)Al[NHSi(NMe2)3]3, 3, and bis(tetrahydrofuran)lithium tetrakis(tris(dimethylamino) silylamino)alanate, Li(THF)2+[((Me2N)3SiNH)4Al]–, 6, is reported, together with the crystal structures of 2, 3 and 6. Tris(dimethylamino)alane, ((Me2N)3SiNH)3Al, was obtained by reaction of tris(dimethylamino)silylamine with aluminium triethyl. The ammonolytic gelation of 3 to an imidoaluminosilicate gel is also described.
Journal title :
DALTON TRANSACTIONS
Journal title :
DALTON TRANSACTIONS
Serial Year :
2003
Link To Document :
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