Record number :
Title of article :
Improved synthesis and hydrogen storage of a microporous metal–organic framework material
Author/Authors :
Cheng، نويسنده , , Shaojuan and Liu، نويسنده , , Shaobing and Zhao، نويسنده , , Qiang and Li، نويسنده , , Jinping، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2009
Pages :
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Abstract :
A microporous metal–organic framework MOF-5 [Zn4O(BDC)3, BDC = 1,4-benzenedicarboxylic] was synthesized with and without H2O2 by improved methods based on the previous studies. The obtained materials were characterized by X-ray diffraction, scanning electron microscopy and nitrogen adsorption, and their hydrogen storage capacities were measured. The synthesis experiments showed that H2O2 favored the growth of high quality sample, large pore volume and high specific surface area. The measurements of hydrogen storage indicated that the sample with higher specific surface area and large pore volume showed better hydrogen storage behavior than other samples. It was suggested that specific surface area and pore volume influenced the capacity of hydrogen storage for MOF-5 material.
Keywords :
MOF-5 , Metal–organic framework , Synthesis , Hydrogen storage
Journal title :
Energy Conversion and Management
Journal title :
Energy Conversion and Management
Serial Year :
Link To Document :