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Title of article :
Thermal effects on the electric deflection of toluene molecules
Author/Authors :
Carrera، نويسنده , , ءlvaro and Mobbili، نويسنده , , Marcos and Moriena، نويسنده , , Gustavo and Marceca، نويسنده , , Ernesto، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
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Abstract :
A series of precise electric deflection experiments were done on a supersonic beam of toluene molecules in several expansion conditions and field strengths. We analyzed the effect of a gradual rotational cooling on the evolution of the beam profile by use of the available theories of asymmetric-top dipoles in electric fields. We have recorded from non-broadened (warm) to very broad and asymmetric (cold) profiles, and discussed this effect in terms of the Stark perturbation on the rotational motion.
Journal title :
Chemical Physics Letters
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