Record number :
Title of article :
Palladium(II) complex with a potential N4-type Schiff-base ligand as highly efficient catalyst for Suzuki–Miyaura reactions in aqueous media
Author/Authors :
Banik، نويسنده , , Biplab and Tairai، نويسنده , , Archana and Shahnaz، نويسنده , , Nasifa and Das، نويسنده , , Pankaj، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2012
Pages :
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Abstract :
Two new air-stable palladium(II) complexes containing a N4-Schiff-base ligand have been synthesized and investigated as catalysts for the Suzuki–Miyaura reactions. The binuclear complex 2 has proven to be an excellent catalyst for additive-free Suzuki–Miyaura reactions of aryl bromides in neat water at room temperature and aryl chlorides in aqueous-glycerol at 80 °C. Satisfactory to excellent yields of biaryls are obtained with a wide range of substrates with relatively low loading of catalyst.
Keywords :
Room temperature , aryl chlorides , Suzuki–Miyaura reaction , Schiff-base ligand , water , Aqueous-glycerol
Journal title :
Tetrahedron Letters
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Link To Document :