Record number :
1865863
Title of article :
Microwave-assisted, solvent-free oxidative cleavage of α-hydroxyketones
Author/Authors :
Carrera، نويسنده , , Ignacio and Brovetto، نويسنده , , Margarita C. and Ramos، نويسنده , , Juan Carlos and Seoane، نويسنده , , Gustavo A.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2009
Pages :
4
From page :
5399
To page :
5402
Abstract :
The oxidative C–C cleavage of α-hydroxy ketones was found to proceed smoothly in solvent-free, silica-supported sodium metaperiodate, under microwave irradiation. This provides a useful and green synthetic procedure to form the corresponding carboxylic acid and aldehyde in good yields, avoiding the solubility problems of the sodium metaperiodate in organic solvents.
Keywords :
Green-chemistry , ?-Hydroxyketones , Sodium metaperiodate , Microwave-assisted oxidation
Journal title :
Tetrahedron Letters
Serial Year :
2009
Link To Document :
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