Record number :
1858967
Title of article :
Thermo-cage opening of 4-iodo-1-vinylcubane to a novel styrene derivative
Author/Authors :
Carroll، نويسنده , , Vincent M. and Harpp، نويسنده , , David N. and Priefer، نويسنده , , Ronny، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2008
Pages :
4
From page :
2677
To page :
2680
Abstract :
Cubane (1) and its derivatives have been cited for exhibiting unusual properties, including explosive and antiviral activity. An additional characteristic of these compounds is their tendency to undergo cage opening under certain conditions. In our attempt to polymerize 4-iodo-1-vinylcubane (4), 4-vinyl-trans-β-iodostyrene (10) was formed quantitatively. By examining both the thermolytic and Lewis acid-assisted rates, a possible mechanism for the rearrangement of 4→10 has been proposed.
Journal title :
Tetrahedron Letters
Serial Year :
2008
Link To Document :
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