Record number :
1793793
Title of article :
Hydrolysis of phosphodiester catalyzed by analogous dinuclear Cu(II) complex in CTAB micellar solution
Author/Authors :
Cheng، نويسنده , , Si-Qing and Wang، نويسنده , , You-Rong and Yan، نويسنده , , Jian-Fang and Zeng، نويسنده , , Xiancheng، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2007
Pages :
4
From page :
32
To page :
35
Abstract :
The catalytic hydrolysis of bis(p-nitrophenyl) phosphate (BNPP) by metallomicelle composed of analogous Cu(II) complex in CTAB micellar solution was investigated at 30 °C and different pH. The results indicate that the analogous complex with 1:2 ratio of ligand to metal ion in CATB micellar solution is the active species for catalyzing the hydrolysis of BNPP. The ternary complex kinetic model for metallomicellar catalysis was employed to obtain the relative kinetic and thermodynamic parameters for taking apart the mechanism of the catalytic hydrolysis of BNPP.
Keywords :
Catalysis , Metallomicelle , phosphodiester hydrolysis
Journal title :
Colloids and Surfaces A Physicochemical and Engineering Aspects
Journal title :
Colloids and Surfaces A Physicochemical and Engineering Aspects
Serial Year :
2007
Link To Document :
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