Record number :
1777932
Title of article :
On the interpretation of the NEXAFS spectrum of molecular oxygen
Author/Authors :
إgren، نويسنده , , Hans and Yang، نويسنده , , Li and Carravetta، نويسنده , , Vincenzo and Pettersson، نويسنده , , Lars G.M.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 1996
Pages :
7
From page :
21
To page :
27
Abstract :
Calculations with extended basis sets and full intrachannel coupling of discrete and continuum states suggest an alternative interpretation of the NEXAFS spectrum of molecular oxygen. In this interpretation the roles of valence-Rydberg mixing and intrachannel discrete-continuum interaction are stressed at the expense of the exchange splitting mechanism. Calculations indicate that only the doublet-parent channel holds discrete strong transitions with σ∗ character, while the quarter-parent channel contains preferentially Rydberg-like transitions.
Journal title :
Chemical Physics Letters
Journal title :
Chemical Physics Letters
Serial Year :
1996
Link To Document :
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