Title of article :
HCFC-31: the CHClFO2 + NO → CHClFO + NO2 reaction and Cl atom elimination from CHClFO
Bhatnagar، نويسنده , , Ashish and Carr، نويسنده , , Robert W.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 1996
The kinetics and mechanism of the reaction of CHClFO2 radicals with NO were studied by time-resolved mass spectrometric monitoring of the molecular ions of NO2 and NO. The rate constant was determined to be (1.31 ± 0.20) × 10−11 cm3 molecule−1 s−1 at (26 ± 1)°C, and was found to be independent of pressure over the range 6–25 Torr. The CHClFO radicals formed in this reaction were found to dissociate by unimolecular CCl bond scission. The unimolecular rate coefficient for Cl atom loss was estimated to be greater than 3 × 103 s−1 at (26 ± 1)°C.
Journal title :
Chemical Physics Letters