Record number :
1739643
Title of article :
Highly cross-linked thermosetting resin of maleimidobenzoxazine functionalized with benzocyclobutene
Author/Authors :
Cheng، نويسنده , , Yuanrong and Qi، نويسنده , , Tianke and Jin، نويسنده , , Yunxia and Deng، نويسنده , , Dunying and Xiao، نويسنده , , Fei، نويسنده ,
Issue Information :
دوهفته نامه با شماره پیاپی سال 2013
Pages :
5
From page :
143
To page :
147
Abstract :
Maleimidobenzoxazine monomer functionalized with benzocyclobutene (BCB) and its cured resin has been successfully prepared. BCB-modified maleimidobenzoxazine monomer (HMI–AB) was synthesized by the reaction of 4-aminobenzocyclobutene (AMBCB), p-hydroxyphenylmaleimide (HMI) and paraformaldehyde in dioxane under reflux. Fourier transform infrared spectroscopy (FTIR), 1H and 13C nuclear magnetic resonance spectroscopy (NMR) were used to characterize the structure of the monomer. The monomer HMI–AB possesses three kinds of polymerizable functional groups of BCB, maleimide and benzoxazine. The polymerization behavior of the monomer is studied by differential scanning calorimetry (DSC) and FTIR. DMA study demonstrates that the cured resin show high storage modulus and high Tg at ca. 350 °C. TGA study shows that the cured resin possess good thermal stability.
Keywords :
Benzocyclobutene , Benzoxazine , maleimide
Journal title :
Polymer
Journal title :
Polymer
Serial Year :
2013
Link To Document :
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