Record number :
1732978
Title of article :
Retarded anionic polymerization (RAP) of styrene and dienes
Author/Authors :
Carlotti، نويسنده , , Stéphane and Desbois، نويسنده , , Philippe and Warzelhan، نويسنده , , Volker and Deffieux، نويسنده , , Alain، نويسنده ,
Issue Information :
دوهفته نامه با شماره پیاپی سال 2009
Pages :
11
From page :
3057
To page :
3067
Abstract :
The possibilities to achieve a quantitative living-like anionic polymerization of styrene and dienes in the absence of solvent and at elevated temperature and using inexpensive initiating systems were explored to make the anionic polymerization competitive with industrial radical processes and allow the industrial production of anionic polystyrene (PS). It implied at first to control the reactivity and stability of initiating and propagating active species in such unusual operating conditions. To achieve these goals the so-called styrene and butadiene “Retarded Anionic Polymerization” (RAP) have been developed. This review focuses on the description of different bimetallic anionic polymerization systems which are able to approach or fulfill the industrial conditions for styrene and dienes anionic polymerizations.
Keywords :
styrene , Retarded anionic polymerization , butadiene , ate complex
Journal title :
Polymer
Serial Year :
2009
Link To Document :
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