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Title of article :
Limits of quantitation — Yet another suggestion
Author/Authors :
Carlson، نويسنده , , Jill and Wysoczanski، نويسنده , , Artur and Voigtman، نويسنده , , Edward، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2014
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Abstract :
The work presented herein suggests that the limit of quantitation concept may be rendered substantially less ambiguous and ultimately more useful as a figure of merit by basing it upon the significant figure and relative measurement error ideas due to Coleman, Auses and Gram, coupled with the correct instantiation of Currieʹs detection limit methodology. Simple theoretical results are presented for a linear, univariate chemical measurement system with homoscedastic Gaussian noise, and these are tested against both Monte Carlo computer simulations and laser-excited molecular fluorescence experimental results. Good agreement among experiment, theory and simulation is obtained and an easy extension to linearly heteroscedastic Gaussian noise is also outlined.
Keywords :
Limit of quantitation , Quantitation limit , detection limits
Journal title :
Spectrochimica Acta Part B Atomic Spectroscopy
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Link To Document :