Record number :
Title of article :
Hydrazinoazadipeptides as aromatic solvent gelators
Author/Authors :
Carré، نويسنده , , Annie and Le Grel، نويسنده , , Philippe and Baudy-Flocʹh، نويسنده , , Michèle، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Pages :
From page :
To page :
Abstract :
In the presence of a small amount of HCl, hydrazinoazadipeptides form thermoreversible physical gels with aromatic solvents. These gels are stable to 70–90°C, and can be stored for months. Electron microscopy reveals that in these solvents, pseudopeptides self-assemble into elongated and very thin fibers, which in turn form a three-dimensional network that traps solvent molecules. Infrared studies showed that aggregation is accompanied by the formation of a hydrogen-bonded network between NH and CO of the hydrazinopeptides.
Keywords :
Electron microscopy , Hydrogen bond , Gel , hydrazinoazapeptides
Journal title :
Tetrahedron Letters
Serial Year :
Link To Document :