Record number :
Title of article :
Unexpected nuclear formylation and acetylation of some nitroanilines with dimethyl sulfoxide in the presence of a strong base
Author/Authors :
Kawakami، نويسنده , , Takehiko and Suzuki، نويسنده , , Hitomi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Pages :
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Abstract :
When treated with a strong base such as KOtBu or NaH in dimethyl sulfoxide at room temperature, 2,4-dinitro-, 2-cyano-4-nitro- and 4-cyano-2-nitroanilines were found to undergo regiospecific acylation at the 3-position to afford the corresponding 3-formyl or 3-acetyl derivatives in fair to moderate yields.
Keywords :
Nitro compounds , acylation , sulfoxides , arenes , carbanions
Journal title :
Tetrahedron Letters
Link To Document :