Record number :
1638191
Title of article :
Insertion of metallated epoxides into zirconacycles
Author/Authors :
Kasatkin، نويسنده , , Alexander N. and Whitby، نويسنده , , Richard J.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Pages :
6
From page :
5275
To page :
5280
Abstract :
Metallated epoxides (epoxysilanes, epoxynitriles, epoxystyrene) insert efficiently into zirconacycles via a 1,2-metallate rearrangement to form intermediates which eliminate Cp2Zr(R)O− to afford substituted alkenes.
Keywords :
Silicon , alkenes , zirconium , zirconacycles , carbenoids , Nitriles
Journal title :
Tetrahedron Letters
Link To Document :