Fe(III)/Cu(II) mediated 5- and 6-exo oxidative ring expansion/cyclisation of cyclopropyl ethers: studies towards dictyol C and α-eudesmol
Booker-Milburn، نويسنده , , Kevin L. and Cox، نويسنده , , Brian P. Grady، نويسنده , , Mick and Halley، نويسنده , , Frank and Marrison، نويسنده , , Shaun، نويسنده ,
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هفته نامه با شماره پیاپی سال 2000
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The outcome of oxidative ring expansion/cyclisation of cyclopropanes with a mixed Fe(III)/Cu(II) system was found to be dependent on the mode of cyclisation. When 6-exo cyclisation was attempted unusual products resulting from oxidation of ring opened primary radicals were obtained.