Record number :
1637904
Title of article :
Unexpected conversion of vinyl sulfoxides into carbonyl compounds by means of iodotrimethylsilane
Author/Authors :
Aversa، نويسنده , , Maria C and Barattucci، نويسنده , , Anna and Bonaccorsi، نويسنده , , Paola and Bruno، نويسنده , , Giuseppe and Giannetto، نويسنده , , Placido and Policicchio، نويسنده , , Manuela، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
Pages :
5
From page :
4441
To page :
4445
Abstract :
The unexpected and previously unknown TMSI-promoted conversion of α,β-unsaturated sulfoxides into carbonyl compounds and disulfides is described. It occurs in good yields under mild conditions. The examples provided support the generality and efficiency of this procedure which acts as a good method for removing the sulfinyl group with the advantage of transforming the vinyl sulfoxides into carbonyl compounds.
Keywords :
Desulfurization , iodotrimethylsilane , sulfoxides , carbonyl compounds
Journal title :
Tetrahedron Letters
Link To Document :