Title of article :
The ‘Hirao reduction’ revisited: a procedure for the synthesis of terminal vinyl bromides by the reduction of 1,1-dibromoalkenes
Abbas، نويسنده , , Sahar and Hayes، نويسنده , , Christopher J and Worden، نويسنده , , Stephen، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2000
A convenient procedure for the synthesis of vinyl bromides is described, which involves the selective reduction of the corresponding 1,1-dibromoalkenes with dimethylphosphite and triethylamine. The 1,1-dibromoalkenes are obtained in excellent yields from the corresponding aldehydes via olefination with carbon tetrabromide and triphenylphosphine.
Journal title :