Record number :
Title of article :
Radical scavengers: A practical solution to the reproducibility issue in the fluoridation of diaryliodonium salts
Author/Authors :
Carroll، نويسنده , , Michael A. and Nairne، نويسنده , , James and Smith، نويسنده , , Graham and Widdowson، نويسنده , , David A.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2007
Pages :
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Abstract :
The addition of radical scavengers to the fluoridation of diaryliodonium salts was demonstrated to improve significantly both the reproducibility of the process and the material yield of the desired fluoroarene products. It was also established that the selectivity of the process was not influenced by the presence of the radical scavengers. TEMPO and galvinoxyl were found to be the most suitable radical scavengers in the fluoridation process allowing the methodology to be used routinely for the first time.
Keywords :
fluorination , Fluorine-18 , hypervalent iodine , Fluorinated aromatics
Journal title :
Journal of Fluorine Chemistry
Serial Year :
Link To Document :