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Title of article :
Diffusion in bulk-metallic glass-forming Pd–Cu–Ni–P alloys: From the glass to the equilibrium melt
Author/Authors :
Rنtzke، نويسنده , , K. and Zِllmer، نويسنده , , V. and Bartsch، نويسنده , , A. and Meyer، نويسنده , , A. and Faupel، نويسنده , , F.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2007
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Abstract :
Since the discovery of bulk-metallic glasses there has been considerable research effort on these systems, in particular with respect to mass transport. Now the undercooled melt between the melting temperature and the caloric glass transition temperature, which has not been accessible before due to the rapid onset of crystallization, can be investigated and theories can be tested. Here we report on radiotracer diffusion measurements in metallic bulk-glass-forming Pd–Cu–Ni–P alloys. Serial sectioning was performed by grinding and ion-beam sputtering. The time, temperature as well as the mass dependence, expressed in terms of the isotope effect E, of Co-diffusion were investigated. In the glassy state as well as in the deeply supercooled state below the critical temperature Tc, where the mode coupling theory predicts a freezing-in of liquid-like motion, the experimentally determined very small isotope effects indicate a highly collective hopping mechanism involving some ten atoms. Below Tc the temperature dependence shows Arrhenius-type behavior with an effective activation enthalpy of 3.2 eV. Above Tc the onset of liquid-like motion is evidenced by a gradual drop of the effective activation energy and by the validity of the Stokes–Einstein equation, which is found to break down below Tc. This strongly supports the mode coupling scenario. The Stokes–Einstein equation is presently tested for other constituents of the alloy. The Co isotope effect measurements, which have never been carried out near Tc in any material, show atomic transport up to the equilibrium melt to be far away from the hydrodynamic regime of uncorrelated binary collisions.
Keywords :
Stokes–Einstein , isotope effect , Mode-coupling theory , diffusion
Journal title :
Journal of Non-Crystalline Solids
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