Record number :
1377983
Title of article :
Photolysis of dicarbonyl(cyclopentadiene)rhodium complexes with a pendent alkyne unit
Author/Authors :
Carsten Schaefer، نويسنده , , Rolf Gleiter، نويسنده , , Frank Rominger، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2007
Pages :
6
From page :
4281
To page :
4286
Abstract :
The syntheses of dicarbonyl[1-(5,5-dimethylhex-3-inyl)-3-phenylcyclopentadienyl]rhodium (7) and its congeners 8 and 9 are reported. Photolysis of 8 and 9 leads to a replacement of one CO ligand by the tethered alkyne unit, yielding 16, and to the dirhodium complexes 17 and 18. The structural assignment of 17 and 18 is based on X-ray studies. The photolysis of 9 leads to 19 and 20.
Keywords :
Rhodiumdicarbonyl complexes , alkynes , Dirhodium carbon clusters , Photolysis
Journal title :
Journal of Organometallic Chemistry
Serial Year :
2007
Link To Document :
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