Record number :
1375264
Title of article :
Synthesis and thermal reaction of hydrido(selenolato) platinum(II) complex having a 9,10,11,12,14,15-hexahydro-9,10[3′,4′]-furanoanthracenyl group
Author/Authors :
Norio Nakata، نويسنده , , Yuki Yamaguchi، نويسنده , , Akihiko Ishii، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2010
Pages :
4
From page :
970
To page :
973
Abstract :
The oxidative addition of selenol, HhfSeH (2, Hhf = 9,10,11,12,14,15-hexahydro-9,10[3′,4′]-furanoanthracenyl) with [Pt(η2-nb)(Ph3P)2] (nb = norbornene) in toluene afforded the corresponding hydrido(selenolato) Pt(II) complex [cis-PtH(SeHhf)(Ph3P)2] (3) as a stable compound. Refluxing a xylene solution of 3 produced two isomers of five-membered selenaplatinacycles 4 in moderate yield as an inseparable mixture. In addition, the molecular structures of HhfSeH 2 and the minor selenaplatinacycle 4a were determined by X-ray crystallography.
Keywords :
Platinum , Selenol , Hydrido complex , Thermal reaction , Selenaplatinacycle
Journal title :
Journal of Organometallic Chemistry
Link To Document :