Record number :
1375220
Title of article :
Palladium-catalyzed asymmetric allylic substitution using planar chiral hydrazone ligands
Author/Authors :
Takashi Mino، نويسنده , , Teruhiro Ogawa، نويسنده , , Masakazu Yamashita، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2003
Pages :
5
From page :
122
To page :
126
Abstract :
Palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate (3) with a dimethyl malonate–BSA–LiOAc system has been successfully carried out in the presence of planar chiral phosphine-hydrazone ligands such as 2a in good yields with good enantioselectivities (up to 96% ee).
Keywords :
Palladium , Hydrazone , Ferrocene , Asymmetric catalysis , Allylic Alkylation , Allylic amination
Journal title :
Journal of Organometallic Chemistry
Link To Document :