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Title of article :
Synthesis, structure, and reaction of tricoordinate stibine and tetracoordinate stiboranide
Author/Authors :
Xin-Dong Jiang، نويسنده , , Yohsuke Yamamoto، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2010
Pages :
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Abstract :
Tricoordinate stibine 1 and tetracoordinate stiboranide 2a were synthesized by utilizing SbCl3. The structure of 2a was confirmed by X-ray analysis. The interconversion between 1 and 2 could be achieved by BrNEt4 and NaH or BuLi. The pentacoordinate apicophilic stiborane 6 was prepared from 1. Due to steric repulsion between the TIP group and the aromatic ring, the C1–Sb–C2 angle of 6b was narrowed by 4.4° compared to that of 6a by X-ray analysis.
Keywords :
Apicophilic , Isomerization , Berry pseudorotation , Stiborane , Stiboranide
Journal title :
Journal of Organometallic Chemistry
Link To Document :