Record number :
1375191
Title of article :
Preparation of sila-functional 3-sila-1-thiacyclohexanes
Author/Authors :
Svetlana V. Kirpichenko، نويسنده , , Aleksander I. Albanov، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2010
Pages :
4
From page :
663
To page :
666
Abstract :
First sila-functional heterocycles 7 and 9 with Si and S atoms in 1,3-position bearing the reactive X group at silicon (X = i-PrO, F) were readily prepared from the corresponding phenyl-protected cycle 6 in good yields via Ph–Si bond cleavage by electrophilic reagents. Treatment of i-propoxy derivative 7 with LiAlH4 gave heterocycle 8 with Si–H bond.
Keywords :
Silathiacyclohexanes , Synthesis , Protecting group , Silicon
Journal title :
Journal of Organometallic Chemistry
Link To Document :