Record number :
1374880
Title of article :
Bicyclo[2.2.2]octanes HC(SiMe2E)3MR (E=S, Se; M=Si, Ge, Sn; R=Me, Ph, Vi)
Author/Authors :
Uwe Herzog، نويسنده , , Gerd Rheinwald، نويسنده , , Horst Borrmann، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2002
Pages :
9
From page :
27
To page :
35
Abstract :
The reactions of 1:1 mixtures of the trisilylmethane HC(SiMe2Cl)3 (1b) and organo Group 14 trichlorides (RMCl3, R=Me, Ph, vinyl (Vi); M=Si, Ge, Sn) with Li2E (E=S, Se) in THF yielded the new bicyclo[2.2.2]octanes HC(SiMe2E)3MR (2a–6b). The products were identified by GC–MS and multinuclear NMR spectroscopy. Trends of the NMR data are discussed. The molecular structures of HC(SiMe2S)3SiMe (2a), HC(SiMe2S)3SiPh (3a), HC(SiMe2Se)3SiVi (4b) and HC(SiMe2Se)3GeMe (5b) are reported.
Journal title :
Journal of Organometallic Chemistry
Link To Document :