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Title of article :
A novel synthetic route to pentaalkylcyclopentadienylgallium(I) compounds
Author/Authors :
Peter Jutzi، نويسنده , , Lars Oliver Schebaum، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2002
Pages :
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Abstract :
The reaction of ‘GaI’ with potassium cyclopentadienides allows a simple access to cyclopentadienylgallium(I)-complexes. Thus, the compounds Me5C5Ga 1 and Me4EtC5Ga 2 have been prepared in high yields. Performing the synthesis of ‘GaI’ under ultrasonic conditions not in toluene but in benzene as solvent, avoids the formation of benzyl iodide as side product.
Keywords :
Gallium , Me4EtC5Ga , Greenיs GaI , Me5C5Ga
Journal title :
Journal of Organometallic Chemistry
Link To Document :