Record number :
Title of article :
Synthesis and reactivity of transition metal complexes containing halogenated boryl ligands
Author/Authors :
S. Aldridge، نويسنده , , R.J Calder، نويسنده , , R.E. Baghurst، نويسنده , , M.E. Light، نويسنده , , M.B. Hursthouse، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2002
Pages :
From page :
To page :
Abstract :
The synthesis and characterization of iron and manganese complexes containing the tetrachlorocatecholboryl (BO2C6Cl4) ligand are reported. Crystallographic study of the methylcyclopentadienyl derivative (η5-C5H4Me)Fe(CO)2BO2C6Cl4 allows comparison of structure and bonding with related complexes of the type (η5-C5R5)Fe(CO)2B(OR)2 and reveals that the relative orientation of (η5-C5H4Me)Fe(CO)2 and BO2C6Cl4 moieties is influenced by intramolecular CH⋯O hydrogen bonding. Additionally, an alternative route to catecholboryl complexes from dilithiocatechol is reported.
Keywords :
Boryl , Boron , manganese , Hydrogen bond , Substitution , Iron
Journal title :
Journal of Organometallic Chemistry
Link To Document :