Record number :
1373941
Title of article :
Unsolvated [KFl(SiPh3)]n (Fl = fluorenyl): A supramolecular chain structure assembled exclusively through K⋯C–π-bonding
Author/Authors :
Ahmad Zaeni، نويسنده , , Falk Olbrich، نويسنده , , Cristian G. Hrib، نويسنده , , Frank T. Edelmann، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2011
Pages :
4
From page :
1935
To page :
1938
Abstract :
Unsolvated potassium 9-triphenylsilylfluorenide, [KFl(SiPh3)]n (3, Fl = fluorenyl), has been prepared in 89% yield by metalation of 9-fluorenyltriphenylsilane (2) with potassium hydride in toluene/THF and structurally characterized by X-ray diffraction. In the solid state, compound 3 comprises a linear chain structure. Due to the absence of coordinating solvent molecules, supramolecular self-assembly occurs solely via K⋯C–π-bonding.
Keywords :
Fluorene , Potassium , Fluorenyl ligands , X-ray structure , Silicon
Journal title :
Journal of Organometallic Chemistry
Link To Document :