Record number :
1370739
Title of article :
The application of Pd-complexes of diphenylphosphinoferrocenyloxazoline ligands to catalytic enantioselective allylic amination
Author/Authors :
Yvonne M Malone، نويسنده , , Patrick J Guiry، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2000
Pages :
6
From page :
110
To page :
115
Abstract :
The preparation of cationic palladium (η3-C3H5) complexes, possessing an enantiopure diphenylphosphinoferrocenyloxazoline unit, is described. These complexes were applied to the enantioselective amination of the test substrate, ethyl (2E)-1,3-diphenylprop-2-enyl carbonate, with benzylamine in moderate to high conversions with enantioselectivities of up to 72% for the (S)-valinol derived oxazoline complex. Enantioselectivities of up to 37% were obtained for the (S)-tert-leucinol derived oxazoline complex.
Keywords :
Allylic amination , Diphenylphosphinoferrocenyloxazoline ligands , Palladium catalysis
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
Serial Year :
2000
Link To Document :
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