Record number :
1333350
Title of article :
Synthesis, crystal structure, and nonlinear optical properties of Bi2Cu5B4O14
Author/Authors :
Shilie Pan، نويسنده , , Jared P. Smit، نويسنده , , Michael R. Marvel، نويسنده , , Evan S. Stampler، نويسنده , , Jacob M. Haag، نويسنده , , Jaewook Baek، نويسنده , , P. Shiv Halasyamani، نويسنده , , Kenneth R. Poeppelmeier، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Pages :
5
From page :
2087
To page :
2091
Abstract :
Bi2Cu5B4O14 crystallizes in the noncentrosymmetric triclinic space group P1 (No. 1) with cell parameters a=10.1381(11) Å, b=9.3917(11) Å, c=3.4566(4) Å, α=105.570(2)°, β=92.275(2)°, γ=107.783(2)°, Z=1 and R1=0.0401 and wR2=0.0980. It is a layered structure that is built up from sheets of rectangular CuO4 and trigonal BO3 groups. The sheets are connected by infinite chains of edge shared BiO6 polyhedra that intersect the bc plane at an angle slightly greater than 90°. The second-harmonic generation efficiency of Bi2Cu5B4O14, using 1064 nm radiation, is about one half times that of KH2PO4.
Keywords :
Nonlinear optical properties , Crystal growth , crystal structure , Oxide
Journal title :
JOURNAL OF SOLID STATE CHEMISTRY
Link To Document :