Record number :
1331941
Title of article :
Layer-type organosilver(I) complexes assembled with nitrate and functionalized phenylethynide ligands
Author/Authors :
Cheng، نويسنده , , Ping-Shing and Hau، نويسنده , , Sam C.K. and Mak، نويسنده , , Thomas C.W.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2013
Pages :
10
From page :
110
To page :
119
Abstract :
A series of seven silver(I) nitrate complexes containing new ligands each composed of a functionalized phenyl nucleus bearing a terminal ethynyl substituent has been synthesized and characterized by single-crystal X-ray analysis. The coordination preferences of the ethynide ligand with respect to the cyano-substituent at variable positions proved to be dominant factors in directing the construction of multi-dimensional organosilver(I) networks, which are consolidated by weak intermolecular interactions in supramolecular assembly.
Keywords :
Argentophilicity , ?–? Stacking , Multinuclear metal–ligand supramolecular synthon , Silver ethynide bonding , Organosilver(I) complex , Supramolecular assembly
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
Serial Year :
2013
Link To Document :
بازگشت