Record number :
1331094
Title of article :
Two novel 3-D coordination polymers based on isonicotinic acid: Syntheses, crystal structures and fluorescence
Author/Authors :
Bing Liu، نويسنده , , Ling Xu، نويسنده , , Guocong Guo، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2006
Pages :
8
From page :
883
To page :
890
Abstract :
The hydrothermal reactions of isonicotinic acid (HIso) and metal salts yielded two novel 3-D coordination polymers {[Cu4(Iso)4(μ3-O)2(C2H5OH)2]·2C2H5OH·C2H6N4}n (1), {[Cd(Iso)2(H2O)]·OHCCHO}n (2), in which 1 was constructed from 32-membered rings and 3-D interpenetrating network of 2 from 42-membered rings. The fluorescent characterizations show the emissions at 565 nm for 1 and 440 nm for 2 possibly assigned to LMCT and IL, respectively.
Keywords :
Coordination polymers , Isonicotinic acid , fluorescence , structure
Journal title :
JOURNAL OF SOLID STATE CHEMISTRY
Link To Document :