Record number :
1318294
Title of article :
Polyoxometalates functioned as ligands: Synthesis and crystal structure of a new hybrid compound constructed from metatungstate and metal complex units
Author/Authors :
Bangbo Yan، نويسنده , , Yanfen Li، نويسنده , , Houyin Zhao، نويسنده , , Wei-Ping Pan، نويسنده , , Sean Parkin، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2009
Pages :
3
From page :
1139
To page :
1141
Abstract :
A new organic–inorganic hybrid compound, [Zn(bpy)3]1.5[H3W12O40Zn(bpy)2(H2O)]·0.5H2O (bpy = 2,2′-bipyridine) has been synthesized hydrothermally from ZnCl2, Na6[H2W12O40], and 2,2′-bipyridine, and has been analyzed using X-ray crystallography, thermogravimetric analysis and UV–Vis spectroscopy. The compound contains an anionic complex [H3W12O40Zn(bpy)2(H2O)]3− in which α-metatungstate ion [H3W12O40]5− coordinated to a [Zn(bpy)2(H2O)]2+ unit through a bridging oxo group.
Keywords :
Hydrothermal synthesis , crystal structure , zinc , Polyoxotungstate
Journal title :
Inorganic Chemistry Communications
Serial Year :
2009
Link To Document :
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