Record number :
1317875
Title of article :
A new self-assembled μ6-sulfato hexanuclear cobalt(II) complex of a symmetric dinucleating ligand: Synthesis and X-ray structural analysis
Author/Authors :
Manindranath Bera، نويسنده , , Ashley B.S. Curtiss، نويسنده , , Ghezai T. Musie، نويسنده , , Douglas R. Powell، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Pages :
4
From page :
1033
To page :
1036
Abstract :
A novel μ6-sulfato hexanuclear cobalt(II) complex, Na2[Co6(Hccdp)3(μ6-SO4)] · 30H2O (1) was isolated from the reaction of CoSO4 · 7H2O with ligand H5ccdp (where H5ccdp = N,N′-Bis[2-carboxybenzomethyl]-N,N′-Bis[carboxymethyl]-1,3-diaminopropan-2-ol) in the presence of NaOH in aqueous-acetonitrile solution and its X-ray crystal structure has been determined. The structure of 1 contains a image core unit which is held together by three heptadentate bridging ligands, Hccdp4−.
Keywords :
Dinucleating bridging ligand , Hexanuclear , Cobalt(II) complex , Self-assembly , X-ray crystal structure
Journal title :
Inorganic Chemistry Communications
Link To Document :