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Title of article :
Synthesis, structure and photoluminescence of a novel palladium(I) compound: [Pd3(μ3-Cl)2(dppp)3][Pd2(μ2-Cl)3(PPh3)2](PPh3)2
Author/Authors :
Geng-Geng Luo، نويسنده , , Rong-Bin Huang، نويسنده , , Li-Rong Lin، نويسنده , , Lan-Sun Zheng، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Pages :
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Abstract :
Pd(PPh3)2Cl2 reacts with PdCl2 and 1,3-bis(diphenylphosphine)propane (dppp) in ethanol–DMF–pyridine mixed solvent to yield a novel palladium(I) compound [Pd3(μ3-Cl)2(dppp)3][Pd2(μ2-Cl)3(PPh3)2](PPh3)2. It features an isolated structure based on [Pd3(μ3-Cl)2(dppp)3]+ cations having triangulo-palladium clusters and [Pd2(μ2-Cl)3(PPh3)2]− anions in which the coordination environment of palladium is an unusual tetrahedral geometry. Its photoluminescence is measured.
Keywords :
Tetrahedral geometry , Trinuclear palladium clusters , Photoluminescence , crystal structure , Palladium(I)
Journal title :
Inorganic Chemistry Communications
Link To Document :