Record number :
Title of article :
A supported Mn(III) catalyst based on d-glucose in the asymmetric epoxidation of styrenes
Author/Authors :
Carmela Borriello، نويسنده , , Raffaella Del Litto، نويسنده , , Achille Panunzi، نويسنده , , Francesco Ruffo، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Pages :
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Abstract :
A strategy for the preparation of a supported ‘salen-type’ Mn(III) catalyst derived from d-glucose is described. The compound has been prepared by introducing the ligand functions at positions 2 and 3 of the sugar, which has been subsequently anchored to a CHO-modified Wang resin through formation of a 4,6-O-benzylidene ring. The activity of the catalyst in the asymmetric epoxidation of styrenes has been investigated by using four different oxidants.
Keywords :
Sugars , manganese , Styrene , Oxidation , Enantioselectivity , Supported catalysis
Journal title :
Inorganic Chemistry Communications
Serial Year :
Link To Document :