Record number :
1314836
Title of article :
NBu4[{Au(C6F5)3}2(μ-PPh2)]: a gold(III) phosphide with a single atom bridging the metallic centers
Author/Authors :
Carmen Blanco، نويسنده , , Eduardo Bolea-Fernandez، نويسنده , , Axel R. Fischer، نويسنده , , Peter G Jones، نويسنده , , Antonio Laguna، نويسنده , , M.Elena Olmos، نويسنده , , M.Dolores Villacampa، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2000
Pages :
3
From page :
163
To page :
165
Abstract :
Reaction of [Au(C6F5)3(PPh2H)] with [Au(C6F5)3(tht)] and NBu4(acac) (acac=acetylacetonate) leads to the synthesis of NBu4[{Au(C6F5)3}2(μ-PPh2)] (1), an unprecedented complex with two gold(III) centers bonded to a unique bridging atom without any other stabilizing effect. The novel di-bridged gold(III) phosphide [Au2(C6F5)4(μ-PPh2)2] (2) is obtained by treatment of diphenylphosphine with [Au2(C6F5)4(μ-Cl)2]. The crystal structures of both derivatives have been determined by X-ray diffraction.
Keywords :
crystal structures , Dinuclear complexes , Gold complexes , Phosphides
Journal title :
Inorganic Chemistry Communications
Serial Year :
2000
Link To Document :
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