Record number :
1082820
Title of article :
Aryl radical cyclisation onto pyrroles
Author/Authors :
Carmen Escolano، نويسنده , , W. Keith Jones، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Pages :
12
From page :
1453
To page :
1464
Abstract :
The intramolecular cyclisation of aryl radicals onto a pyrrole is studied. The cyclisation allows the synthesis of either the spiropyrrolidinyloxindole or the pyrrolo[3,2-c]quinoline skeleton depending on the nature of the protecting group at the N-pyrrole atom. The regiochemistry of the cyclisation is not affected by the substituents on the benzene ring. Some limitations on the utility of tosylmethylisocyanide in pyrrole synthesis are also reported.
Keywords :
Radicals , Cyclisation , regioselection , Natural products , pyrroles
Journal title :
Tetrahedron
Serial Year :
2002
Link To Document :
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