Record number :
1011174
Title of article :
Grand canonical Monte Carlo simulation of isotherm for hydrogen adsorption on nanoporous siliceous zeolites at room temperature
Author/Authors :
Mahmoud Rahmati، نويسنده , , Hamid Modarress، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2009
Pages :
6
From page :
4773
To page :
4778
Abstract :
Zeolites belong to a most prominent class of nanoporous materials which have been considered as potential sorbents for hydrogen storage. The adsorption of hydrogen molecules on purely siliceous zeolites such as ACO, MEP, ASV, ANA, RWY, and RHO, which encompass a range of different pore structures and their chemical compositions has been simulated employing Grand Canonical Monte Carlo (GCMC) procedure for a temperature range of 250–325 K, and a pressure range of 0–10 kbar. The effects of pore structure of zeolites, temperature and pressure on the hydrogen adsorption has been examined. The results clearly show that the number of adsorbed hydrogen molecules at high pressure, only depends on pore diameter, and the temperature effect on the adsorption decreases with decrease in the number of adsorbed of hydrogen molecules.
Keywords :
Hydrogen , Zeolite , Adsorption , Pore structure , Monte Carlo simulation
Journal title :
Applied Surface Science
Link To Document :